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soldering were invented, and by 2500 BC the value of tin was well known for soldering and brazing. Casting techniques were good enough to make human-sized statues and small lost-wax figurines. Metal began to play a part in international relations, especially during Akkadian times (23502200 BC...

www.geology.ucdavis.edu/~cowen/~GEL115/115CH4.html

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